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Synergistic effect of phenyl silicone oil and other lubricants

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The synergistic effect of phenyl silicone oil and other lubricants is mainly manifested in the complementary advantages between different lubricants, which significantly improves lubrication performance, widens the operating temperature range, enhances wear resistance and improves the overall stability of the lubrication system. The following is an analysis of the principle, specific performance and application scenarios of the synergistic effect:

1. Principle of synergistic effect
Molecular structure complementarity
Phenyl silicone oil has a phenyl side chain and a siloxane main chain, and its molecular structure has both flexibility and thermal stability. When mixed with mineral oil, polyether or ester lubricants, the polar groups of phenyl silicone oil can form intermolecular interactions with the non-polar segments of the base oil to optimize the density and load-bearing capacity of the lubricating film.
Lubrication mechanism synergy
Boundary lubrication: Phenyl silicone oil forms an adsorption film on the metal surface to reduce direct contact between metals;
Fluid lubrication: Other lubricants maintain the thickness of the oil film and reduce the friction coefficient.
The combination of the two can cover the range of working conditions from low speed and heavy load to high speed and light load.
Enhanced thermal stability
The high temperature resistance of phenyl silicone oil (such as stability above 250°C) can delay the thermal oxidation degradation of the base oil, while the base oil reduces the viscosity of phenyl silicone oil through dilution and improves low-temperature fluidity.

2. Specific manifestations of synergistic effect
Improved lubrication performance
Reduced friction coefficient: Experiments show that the friction coefficient can be reduced by 20%~30% after phenyl silicone oil is compounded with polyalphaolefin (PAO).
Reduced wear: In the four-ball test, the wear spot diameter of the compounded lubricant is about 30%~50% smaller than that of the single lubricant.
Enhanced extreme pressure performance: The phenyl group of phenyl silicone oil can decompose under high pressure to form a reaction film, which synergizes with sulfur/phosphorus additives to provide extreme pressure protection.
Improved temperature adaptability
Low-temperature fluidity: Phenyl silicone oil (such as low phenyl content models) can reduce the pour point of the lubricant, so that it still maintains fluidity at -70°C.
High temperature stability: In a high temperature environment above 200°C, phenyl silicone oil can inhibit the oxidation and volatilization of the base oil and extend the life of the lubricant.
Anti-aging and corrosion resistance
The antioxidant property of phenyl silicone oil can slow down the increase in the acid value of the base oil and extend the oil change cycle.
The corrosion inhibition effect on non-ferrous metals such as copper and aluminum makes it suitable for precision fields such as electronic equipment and aerospace.

3. Typical application scenarios
Aerospace
Phenyl silicone oil is compounded with perfluoropolyether (PFPE) for lubrication of aircraft engine bearings to meet the wide temperature range requirements of -60℃ to 250℃.
In the lubrication system of spacecraft, phenyl silicone oil and lithium-based grease work together to provide low-torque starting and long-life lubrication.
Automotive industry
Adding 5%~10% phenyl silicone oil to engine lubricating oil can improve the lubrication of turbochargers and reduce cold start wear.
Phenyl silicone oil and polyether are compounded in gear oil to improve the anti-scratch ability of the gearbox under high temperature and high load.
Electronic equipment
In hard disk drives, phenyl silicone oil and fluorinated liquid work together to achieve suspended lubrication of the magnetic head and reduce the risk of collision of the read-write head.
In semiconductor manufacturing equipment, phenyl silicone oil is compounded with perfluorinated compounds to meet the process requirements of high vacuum and low volatility.
Food processing
Phenyl silicone oil is compounded with white oil for chain lubrication of baking equipment, which meets NSF H1 food grade certification.
In filling machinery, compound lubricants can withstand high-temperature steam cleaning and reduce downtime for maintenance.

4. Optimization direction of synergistic effect
Molecular design
Customized compounding schemes are made by adjusting the phenyl content (such as 5%~45%) and viscosity grade.
Introducing functional groups (such as amino and hydroxyl groups) to enhance compatibility with base oils.
Additive synergy
Adding nanoparticles (such as MoS₂ and graphene) to phenyl silicone oil further improves anti-wear performance.
Antioxidants (such as phenols and amines) are used to delay the aging of compound lubricants.
Testing and evaluation
The tribological properties of compound lubricants are systematically evaluated using equipment such as SRV high-frequency reciprocating tester and Falex bite tester.
The thermal stability mechanism of the synergistic effect was characterized by means of thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC).

5. Conclusion
The synergistic effect of phenyl silicone oil and other lubricants originates from its unique molecular structure and lubrication mechanism. By optimizing the compounding ratio and additive system, the comprehensive performance of the lubricant can be significantly improved. In the future, with the development of materials science and tribology, the application prospects of phenyl silicone oil in the field of high-end lubrication will be broader.

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